5,7-Dihydrodibenzo[c,e]thiepine
نویسندگان
چکیده
In the title compound, C(14)H(12)S, the central seven-membered C(6)S ring has a twist-boat conformation. The dihedral angle between the two benzene rings is 52.4 (1)°.
منابع مشابه
11-[3-(Dimethylamino)propyl]-6,11-dihydrodibenzo[b,e]thiepin-11-ol
There are two independent mol-ecules (A and B) in the asymmetric unit of the title compound, C(19)H(23)NOS. In each mol-ecule, the seven-membered thiepine ring is bent into a slightly twisted V-shape. The dihedral angles between the mean planes of the two benzene rings fused to the thiepine ring are 75.7 (5) in mol-ecule A and 73.8 (4)° in mol-ecule B. In both mol-ecules, an intra-molecular O-H...
متن کاملFine-tuning of biaryl dihedral angles: structural characterization of five homologous three-atom bridged biphenyls by X-ray crystallography.
The homologous series of three-atom bridged biaryls comprising 5,7-dihydro-1,2,3,9,10,11-hexamethoxydibenzo[c,e]oxepine, 6,7-dihydro-1,2,3,9,10,11-hexamethoxy-6-methyl-5H-dibenzo[c,e]azepinium chloride, 5,7-dihydro-1,2,3,9,10,11-hexamethoxydibenzo[c,e]thiepine, and the 6-oxide and 6,6-dioxide derivatives of the latter have been characterized by X-ray crystal structure analysis. Within this seri...
متن کامل3,9-Dibromo-5,7-dihydrodibenzo[c,e]oxepine
The title compound, C(14)H(10)Br(2)O, is a biphenyl derivative containing a -CH(2)-O-CH(2)- bridge in the 2,2'-position. The compound displays a twisted conformation with the two benzene rings making a dihedral angle of 45.02 (5)°, while the central seven-membered ring is in a boat conformation. The mol-ecule lies on a crystallographic twofold axis of symmetry passing through the O atom and bis...
متن کاملSynthesis and Antimicrobial Evaluation of Dibenzo[b,e]oxepin-11(6H)-one O-Benzoyloxime Derivatives
A series of dibenzo[b,e]ox(thi)epin-11(6H)-one O-benzoyloximes has been synthesized and structurally elucidated by means of IR, (1)H-NMR, (13)C-NMR, MS, and elemental analysis. The newly developed compounds were screened at concentrations of 200-25 μg/mL for their antibacterial activity against Gram+ve organisms such as Methicillin-Resistant Staphylococcus Aureus (MRSA), Gram-ve organisms such ...
متن کامل3,9-Dibromo-6,7-dihydro-5H-dibenzo[c,e]thiepine
In the title mol-ecule, C(14)H(10)Br(2)S, the two benzene rings form a dihedral angle of 48.35 (14)°. The seven-membered ring adopts a boat conformation. In the crystal structure, mol-ecules are related by translation along the b axis and exhibit C-H⋯π inter-actions.
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009